The complexes have good properties, such as good luminescent properties and obvious antimicrobial activities.It can be used for the synthesis of 2,5dihydrofurans through a straightforward methodology involving a twostep sequence: Ti (III) addition Ag(I) cyclization.In vitro antitumor activity of the NPs was assessed on 4T1 cancer cells using 5dimethylthiazolzyl)2,5diphenyltetrazolium bromide (MTT) assay with and without Xray radiation.
Results showed that Bi 2 S 3 BSABioMTX NPs have excellent anticancer activity, especially following Xray radiation. Developed protocol does not required external additive, oxidant and cocatalyst and wide variety of functional groups can be tolerated. The catalyst is very active at ppm level concentration of Palladium to provided High TON and TOF. Fe 3 O 4 LTyrosinePd has been applied as an efficient recoverable catalyst in the CC and CS coupling reactions in water as a green solvent. The dyad was successfully synthesized and structurally optimized by XRD. The selective sensing of CN and F Ions was confirmed by optical, FTIR, and 1H NMR studies and theoretical density functional calculations. Fe 3 O 4 PTMSTrisCo has been applied as an efficient catalyst for the selective synthesis and oxidation of sulfides. The tetracoordination of nickel atom give rise to a slightly distorted squareplanar geometry. All complexes can be used as efficient molecular eletrocatalysts for hydrogen evolution with TFA as proton source. Specially, 4 exhibits the highest catalytic activity with the turnover frequency (TOF) of 2545.29 s 1. This heterogeneous catalyst was characterized by appropriate analyzes and the catalytic efficiency was investigated in the selective oxidation of sulfides and thiols. Xiao Yu Xie Li Ke Bai 1 Free Conditions InThese reactions can be carried out in solventfree conditions in the presence of hydrogen peroxide with complete selectivity and very high conversion under mild reaction conditions. The present method offers advantages of excellent yields, short reaction times and simple workup. The hydrophobic complex of CdAPDC was extracted in a tunable solvent system which was prepared from a polybasicamine (N, N, N, Ntetramethyl1, 4diaminobutane), decanol and water system. The tunable solvent system has zero ionic strength was converted to homogeneousmonophasic polar hydrophilic phase via exposure to CO 2. Then hydrophobic enriched CdAPDC was back extracted, using HNO 3 and determined by FAAS. The biological activities vary greatly on account of the different Cu(II) numbers and some of them show great antum or activities and highest DNA binding affinities. It was blended with organic phosphorus compound to act as flame retardants for epoxy resins, which exhibited excellent flame retardant efficiency. Their photoluminescence and thermal properties, DFTTDDFT, photovoltaic efficiency in Dye Sensitized Solar Cell (DSSC), cytotoxic effect, apoptosis, autophagy and necrosis type classical cell death were investigated in detail. The coordination ratio and structure of the complexes were further determined by ultraviolet titration experiments. The results show that the coordination ratio of transition metal, alkaline earth metal and ligand is 2:1:1.
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